So I don’t know that I have ever run across a 4 hr working time resin. Best I have seen is 45 minutes. That being said, when I do my resin classes I will make sure we cover the process verbally (usually twice cause I get questions through explanation #1). Then once everyone has a clear understanding of the process we all mix our resin at the same time and I have to split my attention between everyone during the working time. I cap those classes at 5 people so that could be the challenge for you. Also, will this be pressure cured or just air cured? If air cured, then you could do it in stages. like ok, were going to pour color #1, lets all do that simultaneously. then 45 min later switch to color 2, and so on. Not sure if any of this helps.
Regarding mixing the catalyst in varying amounts I have never messed with that. The only person I do know who used to do that at DMS is not longer a member. I do remember them saying that it was a costly endeavor as they had to blow through hundreds of dollars of resin to get their technique down.
Edit- I just saw that you mentioned a 4 hr curing time. Did you mean curing time or open working time. I was assuming you meant working time. Cause most resins have 12-48 hr cure times. 4 hours is a very fast cure time.