Years ago, I took a soap making course in science at DMS. It was excellent, and I’ve been making my own soap for a number of years now.
I’ve done a lot of research on soap making, reading and testing out different formulas and making lots of different batches. You can find al kinds of information on the web including different recipes. I love this software/web application that takes the calculations out of trying different saponification values for different oils when making soap.
I’ve bought dozens of different oils, additives, tints, and scents. I have a large collection of molds and tools, too. I also have a lot of different books on the art and science of making soap.
I bought this book: Scientific Soapmaking: The Chemistry of the Cold Process
and it is excellent. It goes into depth on the saponification process. It has a lot of detail information on the actual scientific process.
Lastly, my wife has eczema. She’s fought it for many years. She’s had various shots, meds and tests, but it was this soap recipe that has made the most impact on relieving her pain and clearing her eczema up:
Eczema Soap.pdf (62.8 KB)
You can increase the superfat ratio in the recipe if you like, too. I’ve tried 5,6, and 7 percent values with varying success. I’ve also added vitamin E, aloe vera gel, titanium dioxide and sodium lactate and other things trying to improve the formula.
My wife has the soap bars in all the bathrooms so she has access anytime she washes. I’ve given many bars away to friends with eczema or who have children with it. It has been successful with quite a few of them. The soap is not a cheap soap.
The oil that has the most impact it NEEM so I usually add it last to the mix so that it is the lion’s share of the superfat oil left in the soap. I believe the fact that there is glycerin left in the soap, which if often removed in commercial soap, it makes a difference, too.
One caveat, is that soapmaking can be dangerous./hazardous if not done with the proper safety equipment and adhering to the proper safety steps. Sodium Hydroxide, Lye, NAOH is a very caustic akali and will burn skin, blind you if it gets into your eyes or explosive if improperly mixed. (Always pur the lye into water not the other way around).