LED spectral width (point at which lower power values are less than 50% of peak value) is typically 50 to more than 100 nm. That is, you won’t really see a ‘line’ rather a distribution centered on the stated LED frequency. (in contrast to a laser or laser diode that has a spectral width of maybe less than one nm).
Thus, when you mix a few LEDs of close frequency, you need a spectrophotometer to really see the net spectral power. You could sort of calculate the spectum, knowing all the LEDs and the powers and the angles, etc, but with the uncertainty of all the variables and whether you are really getting what you think you are getting, the photometer gives you the flux at the level of the exposure area.
I think it is probably wishful thinking to actually get such an instrument. They are really expensive and the money would probably be better spent on other things. Unless we found one on ebay.
But if we got serious and developed a product and wanted to make a bunch, it would be cool to have.